[1]张筱逸,郭健雄,李仙,等.辛烯基胆固醇液晶衍生物合成与相变研究[J].福建工程学院学报,2018,16(04):361-364.[doi:10.3969/j.issn.1672-4348.2018.04.011]
　ZHANG Xiaoyi,GUO Jianxiong,LI Xian,et al.Synthesis and phase transformation of octenyl cholesterol liquid crystal derivatives[J].Journal of FuJian University of Technology,2018,16(04):361-364.[doi:10.3969/j.issn.1672-4348.2018.04.011]
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辛烯基胆固醇液晶衍生物合成与相变研究()
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《福建工程学院学报》[ISSN:2097-3853/CN:35-1351/Z]

卷:
第16卷
期数:
2018年04期
页码:
361-364
栏目:
出版日期:
2018-08-25

文章信息/Info

Title:
Synthesis and phase transformation of octenyl cholesterol liquid crystal derivatives
作者:
张筱逸; 郭健雄; 李仙; 洪艺鸣; 陈凡
福建工程学院土木工程学院
Author(s):
ZHANG Xiaoyi; GUO Jianxiong;  LI Xian;  HONG Yiming;  CHEN Fan
School of Civil Engineering, Fujian University of Technology
关键词:
胆固醇;  液晶;  合成;  性能
Keywords:
cholesterol;  liquid crystal;  synthesis;  properties
分类号:
O621.2
DOI:
10.3969/j.issn.1672-4348.2018.04.011
文献标志码:
A
摘要:
设计合成对-7-辛烯羰氧基苯甲酸(A)和对-7-辛烯羰氧基苯甲酸胆固醇酯(B)，采取红外(FT-IR)、 核磁(1H-NMR)、质谱(MS)及元素分析法对其结构进行表征。用DSC分析B的相变温度，发现在78.3 ℃出现第一个相变峰，在123.4 ℃到达了各向同性的液相，介晶温度范围也较宽。用POM观察B液晶相态，选取90 ℃时进行拍摄出现明显的片状有序排列，说明化合物B具备液晶性能。
Abstract:
The cholesterol benzylalmenoic acid derivative was designed and synthesized. The structure of the product was characterized by FIR, elemental analysis, 1H NMR and 13C NMR. The phase transition temperature of compound B was analyzed with DSC. It was found that the first phase transition peak appeared at 78.3 ℃, the isotropic phase was reached at 123.4 ℃, and the mesogenic temperature range was quite wide. Observation of the phase state of B’s liquid crystals with POM showed obvious orderly arrangement at 90 ℃, indicating that compound B possesses liquid crystal properties.

参考文献/References:

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更新日期/Last Update: 2018-08-25