[1]焦澄远、郑樑、余根鼎（通）、吴诗佳、李静玲.TDI Char制备液体燃料方法[J].福建工程学院学报,2020,18(06):549-552.[doi:10.3969/j.issn.1672-4348.2020.06.007]
　JIAO Chengyuan,ZHENG Liang,YU Gending,et al.A novel method of preparing liquid fuel from TDI Char[J].Journal of FuJian University of Technology,2020,18(06):549-552.[doi:10.3969/j.issn.1672-4348.2020.06.007]
点击复制

TDI Char制备液体燃料方法()
分享到：

《福建工程学院学报》[ISSN:2097-3853/CN:35-1351/Z]

卷:
第18卷
期数:
2020年06期
页码:
549-552
栏目:
出版日期:
2020-12-25

文章信息/Info

Title:
A novel method of preparing liquid fuel from TDI Char
作者:
焦澄远、郑樑、余根鼎（通）、吴诗佳、李静玲
福建工程学院生态环境与城市建设学院
Author(s):
JIAO Chengyuan1; 2;  ZHENG Liang3;  YU Gending1;  WU Shijia1; 2;  LI Jingling
School of Ecological Environment and Urban Construction, Fujian University of Technology
关键词:
甲苯二异氰酸酯; 焦油残渣; 甲醇; 超临界流体; 液体燃料; 绿色化学
Keywords:
toluene diisocyanate;  char;  methanol;  supercritical fluid;  liquid fuel;  green chemistry
分类号:
TQ511
DOI:
10.3969/j.issn.1672-4348.2020.06.007
文献标志码:
A
摘要:
首次提出以甲醇超临界流体用于TDI Char 制备消解液体燃料技术。研究了制备实验条件并进行表征。结果表明，反应温度270 ℃?反应时间120 min 条件下，TDI Char 的消解率达95%。氧弹量热仪实验揭示，所得单位液体燃料的燃烧热值较直接燃烧TDI Char 增加了2.3 倍。
Abstract:
The technique of applying methanol supercritical fluid into the preparation and degradation of liquid fuel with TDI Char was proposed. The experimental preparation conditions were studied and characterized. Results demonstrate that the degradation efficiency of TDI Char reached 95% at approximately 270℃ and with a reaction time of 120 min. The calorimeter experiments revealed that the heat of combustion per unit liquid fuel was significantly increased by 2.3 twice as much as that of direct combustion by TDI Char itself.

参考文献/References:

[1] BERNARDINI J, ANGUILLESI I, COLTELLI M B, et al. Optimizing the lignin based synthesis of flexible polyurethane foams employing reactive liquefying agents[J]. Polymer International, 2015, 64(9): 1235-1244.[2] MIKLS M, BRAHM J, JNOS L. Determination of TDA-tar and TDI-tar content and quantity in TDI synthesis[J]. Mater Sci and En, 2015(40):17-25.[3] ZHANG L, HU Y, WU L, et al. IPA recycling by hydrolysis reaction of TDI residue[J]. Advanced Materials Research, 2014, 1078: 61-64.[4] HAN J, HAN P, JUNG C, et al. Optimization of TDA recycling process for TDI residue using near-critical hydrolysis process[J]. Korean Chemical Engineering Research, 2006, 44(6): 650-658.[5] MIKLS M, BRAHM J, JNOS L. Formation of tars in the TDA-TDI synthesis and experimental study of its removal in the TDI recovery processes[J]. Mater Sci and En, 2015(40):5-16.[6] ABDULAGATOV I, POLIKHRONIDI N, ABDURASHIDOVA A, et al. Thermodynamic properties of methanol in the critical and supercritical regions[J]. International Journal of Thermophysics, 2005, 26(5): 1327-1368.[7] BULGAREVICH D, OTAKE K, SAKO T, et al. Kinetics of the N-alkylation by supercritical methanol[J]. The Journal of Supercritical Fluids, 2003, 26(3): 215-224.[8] GOTO M. Chemical recycling of plastics using sub-and supercritical fluids[J]. The Journal of Supercritical Fluids, 2009, 47(3): 500-507.[9] ALLAN D, DALY J, LIGGAT J. Oxidative and non-oxidative degradation of a TDI-based polyurethane foam: Volatile product and condensed phase characterisation by FTIR and solid state 13C NMR spectroscopy[J]. Polymer Degradation and Stability, 2019, 161: 57-73.

更新日期/Last Update: 2020-12-25