[1]丁翠翠,郑志功,杨加扬,等.双醛羧甲基壳聚糖-SiO2杂化材料改性胶原研究[J].福建工程学院学报,2017,15(06):559-562.[doi:10.3969/j.issn.1672-4348.2017.06.011]
 Ding Cuicui,Zheng Zhigong,Yang Jiayang,et al.The study on the structure and properties of collagen modified by a hybrid material dialdehyde carboxymethyl chitosan-SiO2[J].Journal of FuJian University of Technology,2017,15(06):559-562.[doi:10.3969/j.issn.1672-4348.2017.06.011]
点击复制

双醛羧甲基壳聚糖-SiO2杂化材料改性胶原研究()
分享到:

《福建工程学院学报》[ISSN:2097-3853/CN:35-1351/Z]

卷:
第15卷
期数:
2017年06期
页码:
559-562
栏目:
出版日期:
2017-12-25

文章信息/Info

Title:
The study on the structure and properties of collagen modified by a hybrid material dialdehyde carboxymethyl chitosan-SiO2
作者:
丁翠翠郑志功杨加扬陈家煌张杨张敏
福建工程学院生态环境与城市建设学院
Author(s):
Ding Cuicui Zheng Zhigong Yang Jiayang Chen Jiahuang Zhang Yang Zhang Min
School of Ecological Environment and Urban Construction, Fujian University of Technology
关键词:
双醛羧甲基壳聚糖 二氧化硅 胶原 改性
Keywords:
dialdehyde carboxymethyl chitosan silicon dioxide collagen modification
分类号:
TS727.2
DOI:
10.3969/j.issn.1672-4348.2017.06.011
文献标志码:
A
摘要:
以羧甲基壳聚糖(CMCS)为原料,经氧化后得到双醛羧甲基壳聚糖(DAC),将DAC与氨基化二氧化硅(SiO2-NH2)进行杂化反应得到DAC-SiO2杂化材料,用作胶原的交联改性剂。研究结果表明,不同杂化程度的DAC-SiO2改性剂均不会破坏天然胶原的三股螺旋结构;与DAC-SiO2杂化材料反应后,胶原的热稳定性提高,但当SiO2-NH2与DAC质量比超过1/5时,提高程度略有下降。
Abstract:
Carboxymethyl chitosan was oxidized to obtain dialdehyde carboxymethyl chitosan (DAC), and then DAC was reacted with SiO2-NH2?to get a hybrid material (DAC-SiO2) which was used as a modifying agent for collagen. The studying results indicated that the triple helix structure of native collagen was not destroyed by all kinds of DAC-SiO2, and the thermal stability of collagen was improved after reacting with DAC-SiO2, but the improvement slightly weakened while the weight ratio of SiO2-NH2?and DAC was no less than 1/5.

参考文献/References:

[1] 刘源森,范浩军,夏淳淳,等.以硅化学为基础的环境友好制革技术研究[J].中国皮革,2010,39(11):25-27.
[2] Ryzhenkov AV, Klassen NV, Masalov VM. Features of structure and properties of biopolymer composites with inorganic nanoparticles[J]. Inorganic Materials: Applied Research,2014,5(4):312-317.
[3] 石磊,甄文娟,单志华.双醛纤维素的制备及表征[J].精细化工,2008,25(8):795-798.
[4] 郭明,姚珊珊,高小艳,等.新型双醛淀粉-SiO2杂化材料固载纤维素酶及其酶学性能研究[J].高校化学工程学报,2015,29(6):1407-1414.
[5] 丁翠翠,田荟琳,李国英.利用粘度法和二维红外相关光谱法研究胶原/羟丙甲基纤维素共混物的相互作用[J].功能材料,2012,43(8):992-996.
[6] 康传红, 郭桐, 井立强, 等. 多孔SiO2与TiO2复合纳米材料的制备及光催化性能[J] 无机材料学报,2009,24(2):229-233.
[7] Zhang M, Ding C, Huang L, et al. Interactions of collagen and cellulose in their blends with 1-ethyl-3-methylimidazolium acetate as solvent[J]. Cellulose,2014,21(5):3311-3322.
[8] Zhang M, Ding C, Chen L, et al. Observation of liquid crystalline collagen with atomic force microscopy (AFM) [J]. Journal of Bioresources and Bioproducts,2016,1(3):139-144.
[9] Li C, Tian H, Duan L, et al. Characterization of acylated pepsin-solubilized collagen with better Surface activity[J]. International Journal of Biological Macromolecules,2013,57:92-98.

更新日期/Last Update: 2017-12-25